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Beilstein J. Org. Chem. 2016, 12, 2125–2135, doi:10.3762/bjoc.12.202
Graphical Abstract
Figure 1: Formation of 5-HMF from D-glucose or D-fructose followed by oxidation to 2,5-DFF.
Scheme 1: Protonation of 5-HMF (1a) and 2,5-DFF (2) leading to cationic species A, B, C, D.
Figure 2: X-ray crystal structure of compounds 5a (a), and 5c (b) (ORTEP diagrams, ellipsoid contour of proba...